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c/coa·submitted 1 months ago by u/milos_vanhecke

[Discussion] certificate of analysis is doing more work than we give it credit for

Discussionbranch of 10 comments

certificate of analysis is doing more work than we give it credit for. Change my mind, genuinely — I have no stake in being right about this. How to ask for a batch record without it turning into a negotiation. One email, three requests: the batch-specific certificate for lot X, the method line behind it, and the…

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10 comments, started 1 months ago
u/rania_okonkwo271 points·1 months ago

Related substances itemised individually is a much stronger document than a single total, because it tells you the shape of the impurity profile rather than its size.

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u/milos_trevino76 points·1 months ago

Related substances itemised individually is a much stronger document than a single total, because it tells you the shape of the impurity profile rathe

Adding the bit that always gets missed: the lot on the vial has to match the lot on the page, or none of this applies to your material.

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u/sig_figs_sammod · analytical-27 points·1 months ago

Does the lot on the vial match the lot on the page?

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u/vito_chowdhury72 points·1 months ago

Area percent is the peak area of your compound over the total integrated area, at one wavelength, on one gradient. It is a relative measure of what the detector saw, not a mass fraction of the vial.

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u/nikhil_lindqvist0 points·1 months ago

Related substances itemised individually is a much stronger document than a single total, because it tells you the shape of the impurity profile rathe

Agreed, and the practical version is: ask for the itemised table. If it exists, you get it.

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u/cato_achebe1 point·1 months ago

net peptide content and purity are two different numbers on the same vial

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u/india_generic_g1 point·1 months ago

LC-MS gives you identity; UV purity gives you a relative quantity. A document with the first and not the second, or the reverse, is answering half the question.

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u/low_appetite_lisa1 point·1 months ago

area% is not mass%, and the difference is the whole game

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u/ismael_eriksen1 point·1 months ago

area% is not mass%, and the difference is the whole game

Disagree on this specific point. Two honest labs can resolve that impurity differently and report different numbers.

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[removed]1 point·1 months ago

[removed by moderator]

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How to read a certificate of analysis and what it does and does not tell you. Area% versus mass%, identity versus quantity, water content, related substances, acetate counterions, and the difference between a vendor-supplied COA and an independent test on the vial you actually received.

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